They've been a staple of Hollywood Red Carpets and gossip columns alike for over a decade, but the era of Brangelina has officially come to a shocking and unexpected end with Jolie officially filing for divorce from Pitt after 12 years together, only two of which saw them married.
The news of the divorce broke earlier today with Angelina's filing, and according to TMZ, it was due to a conflict over their kids, Pitt's alleged substance abuse, and anger. Jolie has asked for physical custody of the couple's six children, requesting Pitt only gets visitation, and is not seeking spousal support.
The news is shocking however as the pair have been a staple ever since their controversial start back in 2004, when they met on the set of Mr. And Mrs. Smith, and were spotted together not long after Pitt and then-wife Jennifer Aniston announced their own divorce after five years of marriage.
As those who loved the couple mourn the end of their romance, take a look back at just some of the couple's happier times together: