There will be even more double crossing as 24: Live Another Day moves forward, this time involving a member of Chloe's (Mary Lynn Rajskub) team and Jack Bauer (Kiefer Sutherland).

24: Live Another Day Promotional PHOTOS

24: Live Another Day opened strong with a two-hour premiere Monday night, with Jack Bauer once again teaming up with longtime partner Chloe. With Chloe now working for a WikiLeaks-type of organization, Jack will soon find that a member of Chloe's team intends on double crossing him, as revealed in a new TV Guide spoiler report.

The incident will take place at an unfortunate time in Jack and Chloe's reunion. While Chloe and Jack were at odds throughout the season premiere, Chloe will share some details of what went on over the past four years when she was out of contact with Jack. One of these details is a "heartbreaking" story that serves to explain her new gothic attire and fierce haircut.

Margot Makes A 'Sacrifice' In Her Mission For Revenge on 24: Live Another Day?

Despite Chloe's opening up, the double crossing will take place around this time, making Jack inherent mistrusting of her and her team.

Enstars previously reported that Chloe went through a tragedy in her personal life, which wound up translating to her all-black appearance.

"She's also suffered a personal tragedy," Rajskub told TV Guide previously. "She's in a lot of pain and [is] angry, and that's reflected in her look."

In other 24: Live Another Day news, the season debuted to 8.08 million viewers and a 2.6 in the 18-49 demographic. It was beaten by The Voice and Dancing With the Stars, though it was a big improvement over Fox's past Mondays.

24: Live Another Day airs Mondays at 9 p.m. on Fox.

Watch the promo for the next episode of 24: Live Another Day here: